[(2-Morpholinoethyl)(2-pyridylmethylene)amine]dithiocyanatozinc(II)
نویسنده
چکیده
The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl-amine and ammonium thio-cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal-bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoeth-yl)(2-pyridylmethyl-idene)amine and two N atoms from two thio-cyanate ligands. The morpholine ring adopts a chair configuration.
منابع مشابه
[2-(Piperidin-1-yl)ethylamine]dithiocyanatozinc(II)
In the mononuclear title compound, [Zn(NCS)(2)(C(7)H(16)N(2))], the Zn(II) atom is four-coordinated by two N atoms of the chelating 2-(piperidin-1-yl)ethyl-amine ligand and two N atoms from two thio-cyanate ligands in a distorted tetra-hedral geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯S hydrogen bonds, forming chains along the b axis.
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The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti-ties of 5-bromo-salicylaldehyde, 2-morpholinoethyl-amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol-ec...
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In comparison with the previous refinement of the title complex, [Zn(NCS)(2)(C(12)H(18)N(2)O)], the present redetermination reveals a different location of the non-carbon attached H atom. Whereas in the previous refinement this H atom was modelled as part of a phenol OH group, the present study indicates a zwitterionic Schiff base ligand with a deprotonated OH group and a protonated tertiary am...
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متن کاملBis{(E)-2,4-diiodo-6-[(2-morpholinoethyl)iminomethyl]phenolato}nickel(II)
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